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71.
Denise J. Reed 《地球表面变化过程与地形》1995,20(1):39-48
In order to maintain an elevation in the intertidal zone at which marsh vegetation can survive, vertical accretion of the marsh surface must take place at a rate at least equal to the rate of relative sea-level rise. Net vertical accretion of coastal marshes is a result of interactions between tidal imports, vegetation and depositional processes. All of these factors are affected, directly or indirectly, by alterations in marsh hydrology which might occur as a result of sea-level rise. The overall response of coastal marshes to relative sea-level rise depends upon the relative importance of the inorganic and organic components of the marsh soil and the impact of increased hydroperiod on net accumulation. The varied combination of factors contributing to sediment supply, and their complexity at the scale of individual marshes, means that predicting the response of suspended sediment concentration in marsh floodwater to any changes which may occur as a result of sea-level rise, at anything other than the local scale is unlikely to be accurate. The impact of sea-level rise on net below-ground production is also complex. The sensitivity of certain species to waterlogging and soil chemical changes could result in a change in species composition or the migration of vegetation zones. Consequently, predicting the net impact of sea-level rise on organic matter accumulation is fraught with difficulties and requires improved understanding of interactions between vegetation, soil and hydrologic processes. 相似文献
72.
Three regolith-collapse sinkholes formed near the Dongola Unit School and the Pentecostal Church in the southern Illinois village of Dongola (Union County) during the spring of 1993. The sinkholes appeared over a three-month period that coincided with development of a new municipal well. The new well was drilled through clay-rich, valley-fill sediment into karstified limestone bedrock. The piezometric surface of the limestone aquifer is above land surface, indicating the presence of an upward hydraulic gradient in the valley and that the valley fill is acting as a confining unit. Pumping during development of the well lowered the piezometric surface of the limestone aquifer to an elevation below the base of the valley fill. It is hypothesized that drainage of water from the sediments, the resulting loss of hydrostatic pressure and buoyant force in overlying sediments, increased intergranular pressure, and the initiation of groundwater flow toward the well resulted in rapid sediment transport, subsurface erosion, and collapse of the valley-fill sediment. The sinkholes follow an approximately east-west alignment, which is consistent with one of the two dominant alignments of passages of nearby joint-controlled caves. A constant electrode-separation resistivity survey of the school playground was conducted to locate areas that might contain incipient sinkholes. The survey revealed a positive resistivity anomaly trending N75E in the southern part of the study area. The anomaly is linear, between 5 and 10 m wide, and its trend either intersects or is immediately adjacent to the three sinkholes. The anomaly is interpreted to be a series of pumping-induced cavities in the valley-fill sediments that formed over a preexisting crevice in the karstified bedrock limestone. 相似文献
73.
R.K. Lowry S.J.B. Reed J. Nolan P. Henderson J.V.P. Long 《Earth and Planetary Science Letters》1981,53(1):36-40
An ion-microprobe-based technique has been used to measure lithium tracer-diffusion coefficients (DLi) in an alkali-basaltic melt at 1300, 1350 and 1400°C. The results can be expressed in the form:DLi=7.5 ×10?2exp(?27,600/RT)cm2S?1The results show significantly faster diffusion rates than those previously recorded for other monovalent, divalent and trivalent cations in a tholeiitic melt. Consequently, diffusive transport of ions acting over a given time in a basaltic melt can produce a wider range of transport distance values than hitherto supposed. Hence, it is concluded that great care should be exercised when applying diffusion data to petrological problems. 相似文献
74.
75.
Calculation of multicomponent chemical equilibria and reaction processes in systems involving minerals,gases and an aqueous phase 总被引:1,自引:0,他引:1
Mark H Reed 《Geochimica et cosmochimica acta》1982,46(4):513-528
The compositional characteristics of many geochemical systems which involve the interaction of natural aqueous solutions with minerals and gases are conveniently described using the following thermodynamic components: Cl?, SO4=, HS?, CO3=, H+, Na+, K+, Ca++, Mg++, Fe++, Zn++, Cu+, Al+++, SiO2 and H2O. A set of mass balance and mass action equations equal in number to the number of components plus the number of saturated minerals (and gases) is defined for a specified temperature, pressure and bulk composition. The mass balance equations include terms for minerals, gases and the molalities of aqueous complexes and dissociated species. This set of non-linear equations can be solved with the aid of a computer using'a Newton-Raphson technique. The calculation takes account of aqueous ion complexing, oxidation-reduction equilibria, activity coefficients, non-unit water activity and solid solutions. The use of H+, SO4=, HS? and H2O as components allows straightforward treatment of processes involving oxidation-reduction, evaporation, boiling and changes of total aqueous H+ due to hydrolysis, mineral reaction or temperature change. One product of this approach is a technique for calculating pH at high temperature from measurement of pH at room temperature.By linking a series of discrete overall heterogeneous equilibrium calculations in which incremental changes of bulk composition, temperature or pressure are made, dynamic geochemical processes can be modeled. Example calculations for two such processes are given. These are the heating of seawater from 25° to 300°C and the isothermal irreversible reaction of rhyolite with an aqueous solution at 250°C. 相似文献
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77.
Hg contents ranging from 0.026 to 0.19 and 0.1 to 344 ppm were measured by activation analysis in a number of pyrite and sphalerite samples, respectively. The release of Hg based on stepwise heating shows a correlation with metamorphic grade of the pyrite samples and with Fe content of the sphalerite samples. Experiments were undertaken to study the equilibration of Hg at different temperatures in Hg-doped laboratory prepared ZnS and FeS2. On subsequent volatilization, trends in the Hg release were observed which paralleled those in the sulfide minerals. 相似文献
78.
A controlled petroleum release was conducted to evaluate bioremediation in a wetland near Houston, Texas. The 140-day study was conducted using a randomized, complete block design to test three treatments with six replicates per treatment. The three treatment strategies were inorganic nutrients, inorganic nutrients with an alternative electron acceptor, and a no-action oiled control. Samples were analyzed for petroleum chemistry and inorganic nutrients. These results are discussed in the context of our related research involving toxicology and microbiology at the site during the experiment. To evaluate biodegradation, the targeted compounds were normalized to the conservative compound C3017alpha, 21beta-[H]hopane, thus reducing the effects of spatial heterogeneity and physical transport. The two biostimulation treatments demonstrated statistically-higher rates of biodegradation than the oiled no-action control. For the majority of the experiment, target nutrient levels were maintained. Further research may be warranted to optimize these bioremediation strategies as well as evaluating additional treatment strategies for wetlands and other shoreline systems. 相似文献
79.
Adverse impacts on the health of some fish populations, such as skewed sex distributions, have been noted in surface waters and in laboratory experiments with relatively low concentrations (above 25 ng/L) of natural estrogen (17 beta-estradiol--E2). Sources of E2 to surface and ground waters can include avian, human, and mammalian waste products. The Ozark Plateau Aquifer (OPA) is a karstic basin that receives a significant portion of its water through losing reaches of rivers. Thus, there is a direct connection between surface water and ground water. The OPA was targeted for an E2 study to assess the potential for adverse health effects to aquatic organisms living in the system. Eight springs, which drain the aquifer, were sampled quarterly. The concentrations of E2 in the OPA ranged from 13 to 80 ng/L. For any one sampling event, the concentrations of E2 at the spring waters were statistically similar; however, the concentrations of E2 at all springs varied throughout the year. At Maramec Spring, one of the larger springs, the E2 concentration, was correlated with discharge. Based on the correlation between discharge and E2 concentration, aquatic organisms living in the plateau or in its discharged waters, including the threatened southern cavefish T. subterraneus, are exposed to concentration of E2 above 25 ng/L approximately 60% of the time. This implies that organisms living in karst basins throughout the OPA are likely exposed to E2 concentrations that may adversely impact their reproductive success for a significant portion of each year. 相似文献
80.